Fe-Catalyzed reactions of 2-chloro-1,7-dienes and allylmalonates

Drabina, Pavel; Nečas, David; Sedlák, Miloš; Kotora, Martin

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Fe-Catalyzed reactions of 2-chloro-1,7-dienes and allylmalonates

Drabina, Pavel; Nečas, David; Sedlák, Miloš; Kotora, Martin

10.1016/j.tetlet.2007.04.143

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URI: http://hdl.handle.net/10195/37278

Datum publikování: 2007

Document type: Article

xmlui.ArtifactBrowser.SimpleSearch.filter.source: Tetrahedron Letters. 2007, vol. 48, issue 26

ISSN: 0040-4039

Publisher version: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THS-4NMWPW4-2&_user=640852&_coverDate=06%2F25%2F2007&_rdoc=1&_fmt=high&_orig=search&_origin=search&_sort=d&_docanchor=&view=c&_acct=C000032310&_version=1&_urlVersion=0&_userid=640852&md5=e3d877846c66a410216bb8f09122d25b&searchtype=a

Abstract:

Fe(III)(BIAP)Cl-3 complex catalyzes alkylative cyclization of 2-chloro-1,7-heptadiene in the presence of triethylaluminum. It also catalyzes deallylation of certain 2-allyl-2-substituted malonates under the same reaction conditions. (c) 2007 Elsevier Ltd. All rights reserved.

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