Ligand field calculations, excluding spin-orbit soupling, have been carried out for bent d1 metallocene complexes in C2v symmetry. The application of the results to the interpretation of the d-d electronic spectrum of the representative d1 complex vanadocene dichloride is discussed with particular reference to the relative energy of the five d orbitals.
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p. 25-35
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eng
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Univerzita Pardubice
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dc.relation.ispartof
Scientific papers of the University of Pardubice. Series A, Faculty of Chemical technology. 6 (2000)
eng
dc.rights
open access
eng
dc.subject
ligandy
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dc.subject
nelineární systémy
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dc.subject
Metalloceny
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dc.subject
komplexy
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dc.subject
molekulární orbitaly
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dc.subject
modely
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dc.title
Ligand field model for bent (C(2v))d1 metallocene complexes